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Dmitri was Natasha Romanova's supervisor during her time in the Black Widow Ops Program.

He was present in Moscow when Mr. Yulov explained that her first mission would be to travel to Havana, where another graduate of the Red Room Academy, Marina, had cultivated a relationship with a pair of government agents, Jema and José Comienza, who were looking to defect from Cuba to the United States of America.[1]

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