Appearing in 1st story
- Mikhail Fjodorov (First and only known appearance; dies)
- Eaglestar (First and only known appearance)
- Sofia (First appearance)
- Unnamed employer (Mentioned)
- Nikolay Baskov (First and only known appearance)
- Iron Man (Tony Stark) (Appears on screen)
- Hulk (Bruce Banner) (Appears on screen)
- Thor Odinson (Appears on screen)
- Hammer Industries (Mentioned)
- Captain America (Steve Rogers) (Appears on screen)
- Hawkeye (Clint Barton) (Appears on screen)
Races and Species:
Synopsis for 1st story
Disguised as Tatiana Sokolova, Black Widow works at a night club in Moscow, pursuing the trail of missing Starktech. While she tries to interrogate Mikhail Fjodorov, one of the world's most successful illegal arms dealers, Fjodorov is killed by an unknown woman and Black Widow is forced to leave the club via the roof, fighting several security men. After she gets to a hotel and is waiting for extraction, she is attacked by masked people working for Eaglestar, but overwhelms them and receives a SIM card to reach the mysterious woman she has seen in the night club. Later, Black Widow talks to the woman, who calls herself "Sofia", and learns that she is a "fan" and wants to take over the name "Black Widow".
• A brand-new Black Widow solo adventure from the Marvel Cinematic Universe! • Before Natasha assembles with the Avengers Initiative, see her in this hard-hitting espionage adventure set between the events of IRON MAN 2 and MARVEL’S THE AVENGERS!